By Lisa Saunders Boffa, Bruce M. Novak
content material: The organometallic polymerization of (meth)acrylates : an outline / Lisa Saunders Boffa --
New functions of "carbonylbis(triphenylphosphine)ruthenium" catalysis in polymer synthesis / William P. Weber ... [et al.] --
Transition metal-catalyzed alkyne cycloaddition polymerization / Tetsuo Tsuda --
man made regulate over substituent position on carbon-chain polymers utilizing ring-opening polymerization of small cycloalkanes / J. Penelle --
Nucleophilic polymerization of methyl methacrylate activated by means of a Brønsted acid / Masatoshi Miyamoto ... [et al.] --Modification of polybutadiene by means of transition steel catalysts : hydroacylation of polybutadiene / Chul-Ho Jun ... [et al.] --
Metallocene catalysts used for the hydrogenation of polystyrene-b-polybutadiene-b-polystyrene block copolymers / Raymond Chien-chao Tsiang, Wen-shen Yang, and Ming-der Tsai --
E-glass fiber supported hydrosilation catalysts / L.G. Britcher and J.G. Matisons --
New catalysts for polymerizations of substituted acetylenes / Ben Zhong Tang ... [et al.] --
Addition polymerization of norbornene : catalysis of monocyclopentadienyltitanium compounds activated with methylaluminoxane / Qing Wu, Yingying Lu, and Zejian Lu --
move and isomerization reactions in propylene polymerization with the isospecific, hugely regiospecific rac-Me₂C(3-t-Bu-1-Ind)₂ZrCl₂/MAO catalyst / Isabella Camurati ... [et al.] --
dwelling radical polymerization of acrylates with rhenium(V)-based starting up platforms : ReO₂I(PPh₃)₂/alkyl iodide / Hiroko Uegaki ... [et al.] --
The impression of ligands on copper-mediated atom move radical polymerization / Jianhui Xia, Xuan Zhang, and Krzysztof Matyjaszewski --
Structural chemistry and polymerization task of copper(I) atom move radical polymerization catalysts / Amy T. Levy and Timothy E. Patten --
Atom move polymerization mediated through solid-supported catalysts / David M. Haddleton ... [et al.] --
Mechanistic elements of catalytic chain move polymerization / Johan P.A. Heuts, Darren J. Forster, and Thomas P. Davis.
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Paulasaari thanks the Neste Foundation for fellowship support. ch002 References 1. Levison, J. ; Robinson, S. D. J. Chem. Soc. A 1970, 2947. 2. ; Sonoda, M . ; Chatani, N . Nature 1993, 366, 520. 3. ; Kamatani, An; Sonoda, M . ; Chatani, N . , Bull. Chem. Soc. Jpn. 1995, 68, 62. 4. ; Weber, W. P. Polym. Bull. 1994, 32, 525. 5. Odian, G. Principles of Polymerization, J. Wiley & Sons, New York, NY, 1981; p 82-96. 6. ; Tapsak, M . ; Weber, W. P. Polymer Bull. 1995, 34, 49. 7. Guo. ; Tapsak, M . ; Weber, W.
Chem. Letters 1998, 47. 10. Bovey, F. ; Hood III, F. ; Anderson, E. ; Kornegay, R. L. J. Chem. Phys. 1964, 41, 2042. 11. ; Weber, W. P. Polym. , 1995, 35, 259. 12. ; Weber, W. P. Polym. Bull. 1996, 37, 169. 13. ; Tapsak, M . ; Weber, W. P. in Step-Growth Polymers for High Performance Materials, New Synthetic Methods, Hedrick, J. L,; Labadie, J. ; ACS Symposium Series 624, American Chemical Society, Washington, DC 1996, p 99-112. 14. Kepler, C. ; Londergan, T. M . ; Weber, W. P. Polymer 1998, 40, 765.
U V X^ (e): 1240 (15,250), 327 (33,900). When irradiated at 376 nm (X in exciation scan ), fluroesence was observed at 450 nm. 5 g, 114 mmol) in THF (120 mL). After a non-aqueous work-up, the product was purified by fractional distillation. 1 mm, 15 g, 82% yield was obtained. 00 (sept. 5 Hz). 53. 16. 5 g, 114 mmol). After filtration, the product was purified by fractional distillation. 2 mm, 80% yield was isolated. 02 (sept. 5 Hz). 34. 33. IR v: 2139 Si-H, 1656 C O cm" . UV X nm (s): 269 (1430).