By Hans-Georg Elias
Like such a lot of of its style, this textbook originated from the necessities of educating. whereas lecturing on macromolecular technological know-how as a required topic for chemists and fabrics scientists at the undergraduate, graduate, and postgraduate degrees at Swiss Federal Institute of know-how at Zurich (1960-1971), i wanted a one-volume textbook which handled the entire box of macromolecular technological know-how, from its chemistry and physics to its purposes, in a now not too basic demeanour. This textbook therefore intends to bridge the space among the customarily oversimplified introductory books and the hugely really good texts and monographs that hide in simple terms components of macromolecular technological know-how. this primary English version relies at the 3rd German version (1975), that is approximately forty% varied from the 1st German version (1971), as a result of the swift development in macromolecular technological know-how and the fewer fast schooling of the author. this article intends to survey the complete box of macromolecular technological know-how. Its association effects from the next concerns. The chemical constitution of macromolecular compounds may be autonomous of the strategy of synthesis, not less than within the excellent case. half I is hence thinking about the chemical and actual constitution of macro molecules. houses depend upon constitution. resolution houses are therefore mentioned partially II, good nation homes partially III. There are different purposes for discussing houses ahead of syntheses: for instance, it truly is tricky to less than stand equilibrium polymerization with out wisdom of resolution thermody of the glass temperature, etc.
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Extra resources for Macromolecules: Volume 1 · Structure and Properties
Example text
3. Commercial Synthesis. . . . . . . . 4. Processing. . . . . . . . . . . . . 5. Derivatives . . . . . . . . . . . . 3. Poly(dimethyl butadiene) . . . . . . . . . . 4. Poly(chloroprene) . . . . . . . . . . . . . 5. Poly(cyanoprene) . . . . . . . . . . . . . . 6. Polypentenamer . . . . . . . . . . . . . . . 4. Other Polyhydrocarbons . . . . . . . . . . . . . . 1. Poly(phenylene) . . . . . .
The Penultimate Chain End Effect . . . . . . . 3. Charge Transfer Complexes . . . . . . . . . 4. Kinetics . . . . . . . . . . . . . . . . . . 5. Environmental Influence. . . . . . . . . . . 6. The Q-e Scheme . . . . . . . . . . . . . . 5. Ionic Copolymerization . . . . . . . . . . . . . . 1. Phenomena . . . . . . . . . . . . . . . . 2. Copolymerization Equations . . . . . . . . . 1. Hypotheses . . . . .
1. Titration of Polyelectrolytes . . . . . 2. Ion-Exchange Resins . . . . . . . . 4. Ring-Forming Reactions . . . . . . . . . . 1. Polymer Analog Conversions. . . . . 2. Two-Step Transannular Reactions . . 5. Chain Extension, Branching, and Cross-Linking Reactions . . . . . . . . . . . . . . . . . . . . 1. Block Copolymerization. . . . . . . . . . . 2. Graft Copolymerization . . . . . . . . . . . 3. Cross-Linking Reactions .