By Rudolph D. Deanin (Eds.)
content material: Radial block thermoplastic rubbers / J.R. Haws --
a brand new thermoplastic syndiotactic 1,2-polybutadiene. I. construction, primary homes, and processing / Yasumasa Takeuchi, Akira Sekimoto, and Mitsuo Abe --
a brand new thermoplastic syndiotactic 1,2-polybutadiene. II. purposes / Yasumasa Takeuchi, Akira Sekimoto, and Mitsuo Abe --
K-resin BDS polymer: a brand new transparent influence resistant polystyrene / L.M. Fodor, A.G. Kitchen, and C.C. Biard --
Random copolycarbonates; characterization and comparative homes of polymers containing tetrachlorinated bisphenols / Eugene C. Gilbert and Gordon D. Brindell --
Polyethersulphone--a new extreme temperature engineering thermoplastic / Victor J. Leslie, John B. Rose, George O. Rudkin, and Joseph Feltzin --
Polyphenylene sulfide: a brand new commercial resin / G.C. Bailey and H. Wayne Hill, Jr. --
Polyimides: chemistry, processing, houses / S.L. Kaplan and S.S. Hirsch --
Polyaminobismaleimides / M.A.J. Mallet and F.P. Darmory --
Processable polymides / F.P. Darmory --
Catalytic trimerization of fragrant nitriles for synthesis of polyimide matrix resins / Li-Chen Hsu --
Poly(p-oxybenzoyl) platforms: homopolymer for coatings; copolymers for compression and injection molding / Roger S. hurricane and Steve G. Cottis --
Round-table dialogue / Rudolph D. Deanin.
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Example text
Therefore, processing techniques suitable for these other resins are generally suitable for the BDS resins. In general, their processing characteristics most closely resemble medium Impact polystyrene. The KR01 and K R 0 3 type resins exhibit very low die swell, low warpage and shrinkage comparable to that of general purpose polystyrene (KR01 > GPPS KR03) These resins are present any major d i f f i c u l t i e s . Since they contain both polybutadiene and polystyrene, degradation can occur by two mechanisms: (1) visbreaking of polystyrene and (2) crosslinking of polybutadiene.
Blowmolding(4). Blowmolding equipment used for HDPE may be used with these resins with minor modifications to the dies and molds. Actually, PVC molds with low shrinkage allowances are more suitable than those for HDPE, because the shrinkage characteristics of these resins are similar to those for PVC. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1974. FODOB ET AL. K-Resin BDS Polymer Figure 3. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1974. 48 NEW INDUSTRIAL POLYMERS Either reciprocating screw or continuous parison extrusion may be used.
Foremost among t h e monomers p r e p a r e d from 2,6-DCP, however, a r e t h e b i s p h e n o l i c i n t e r m e d i a t e s . S e v e r a l o f these, along w i t h t h e i r a p p r o p r i a t e chemical abbrev i a t i o n s , a r e i l l u s t r a t e d below: X = CH X = S0 X = CH OCH TCBF TCBS TCBF-0 2 2 2 2 Y Z X = CH -N~CH I OH-* 2 where 2 9 TCBF-MA salts Y = H, Z = CI Y = CH , Z = C H S 0 3 3 4 TCBF (6), TCBS (7) and TCBF-0 (£) have been p r e v i o u s l y d e s c r i b e d ; TCBF-MA and i t s s a l t s , however, a r e new c o m p o s i t i o n s .