The technology of glass and ceramics by Jan Hlavac

By Jan Hlavac

Either in its scope and content material this booklet may be considered as an incredible paintings. -- Glass expertise textual content: English, Czech (translation)

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2. 02 at% Cu. This is the reason why neither Al- nor Cu-containing phases are visible in the last liquid to solidify. 6 Conclusion Using a combination of computational thermodynamics, involving the Calphad method, and selected key experiments reveals intricate details and stunning features of phase transformations in ternary and quaternary alloys with demixing in the liquid phase. Only in the most simple case does the well-known binary monotectic reaction L = L + solid extends into the ternary without producing any invariant monotectic four-phase reaction and the Al–Bi–Sn system is given as an example.

L. (2004) ‘‘Experimental study and thermodynamic re-assessment of the Al-B system’’. Journal of Alloys and Compounds, 384, 168–74. , Mirkovi´c, D. and Schmid-Fetzer, R. (2004) ‘‘Thermodynamic aspects of constitution, grain refining and solidification enthalpies of Al-Ce-Si alloys’’. Metallurgical and Materials Transactions A, 35A, 3349–62. , Mirkovi´c, D. and Schmid-Fetzer, R. (2005) ‘‘Thermodynamic aspects of grain refinement of Al-Si alloys using Ti and B’’. Materials Science and Engineering A, 395, 10–21.

5 binary induces a wetting transition that occurs before solidification of Al–Bi–Cu and Al–Bi–Sn alloys. Acknowledgments This study was supported by the German Research Foundation (DFG) in the Priority Programme ‘‘DFG-SPP 1120: Phase transformations in multicomponent melts’’ under grant HO 1688/8. We are indebted to Prof. Rainer Schmid–Fetzer, Dr Joachim Gr¨obner, and Dr. Djordje Mirkovic for the valuable information and discussions of the phase equilibria in monotectic systems. We thank Mrs References Heidemarie Teichmann, Mrs Gisela Baumann, Ms Karen Friedrich, and Mr Rene Krone for their technical assistance.

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