Novel Functional Materials Based on Cellulose by Haisong Qi

By Haisong Qi

This short provides a evaluate of recent green strategies, layout and functions for novel cellulose-based fabrics, together with regenerated fabrics, composites, nanocellulose and cellulose derivatives. software of those fabrics in shrewdpermanent textiles, packaging, power garage, sensors, gasoline separations, tissue engineering and drug unlock are highlighted.

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Macromol Biosci 4:1105–1112 26. Yan L, Gao Z (2008) Dissolving of cellulose in PEG/NaOH aqueous solution. Cellulose 15:789–796 27. Qi H, Yang Q, Zhang L et al (2011) The dissolution of cellulose in NaOH-based aqueous system by two-step process. Cellulose 18:237–245 28. Cai J, Zhang L, Liu S et al (2008) Dynamic self-assembly induced rapid dissolution of cellulose at low temperatures. Macromolecules 41:9345–9351 29. Cai J, Zhang L, Zhou J et al (2007) Multifilament fibers based on dissolution of cellulose in NaOH/urea aqueous solution: structure and properties.

Yamane C, Saito M, Okajima K (1996) Manufacture of new cellulosic fibers from a spinning bath of an aqueous solution of alkali—soluble cellulose and caustic soda. Part 1. Development of a method for industrial preparation of an aqueous solution of highly soluble cellulose and caustic soda. Sen’i Gakkaish 20. Isogai A, Atalla RH (1998) Dissolution of cellulose in aqueous solutions. Cellulose 5:309–319 21. Egal M, Budtova T, Navard P (2008) The dissolution of microcrystalline cellulose in sodium hydroxide-urea aqueous solutions.

Sponge-like structures are formed when the solvent diffuses out faster than the non-solvent diffuses in [4]. For the regeneration of cellulose from its solution, the exchange of solvent with non-solvent leads to a desolvation of the cellulose molecules and to the supposed reformation of the intra- and intermolecular hydrogen bonds [5]. While most types of regenerated cellulose have crystal form of cellulose II, having antiparallel chain packing, their mechanical and surface chemical properties are known to depend strongly on the type of cellulose solvent and coagulant, as well as the conditions of regeneration such as temperature and time.

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