Advances in Controlled/Living Radical Polymerization by Krzysztof Matyjaszewski

By Krzysztof Matyjaszewski

Provides new advancements in controlled/living radical polymerization in 3 components: atom move radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation move (RAFT). additionally contains synthesis and characterization of many new materials.

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Matyjaszewski,K. J. Am. Chem. Soc. 2002, 124, 8196. (h) Shipp, D. ; Yu, X . Polym. Prepr. (Am. Chem. , Div. Polym. ) 2002, 43(2), 7. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2003. 39 3. 4. 5. ch003 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. (a) Fischer, H . Macromolecules 1997, 30, 5666. (b) Fischer, H . J. Polym. Sci. : Polym. Chem. 1999, 37, 1885. (c) Souaille, M . ; Fischer, H. Macromolecules 2000, 33, 7378. (d) Fischer, H. Chem. Rev. 2001, 101, 3581.

Iodide-Mediated Polymerization The first detailed kinetic study on polymerization with a DT process was presented some time ago for an iodide-mediated polymerization of styrene. 26) as a DT agent and BPO as a conventional initiator. The polymerization followed the first-order kinetics and gave the same R as in the absence of the DT agent, thus confirming eq 3. The PDI equation 6 with the transfer constant C = hJkp determined independently (Table lc) is given by the dotted line in Figure 4a. The experimental data for varying BPO concentrations fall on the same line, thus confirming the theory on an absolute scale.

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